Recent Advances in the Catalytic Enantioselective Reformatsky Reaction
نویسندگان
چکیده
منابع مشابه
Catalytic enantioselective Reformatsky reaction with ketones.
Chiral tertiary alcohols were obtained with good yields and enantioselectivities via a catalytic Reformatsky reaction with ketones, including the challenging diaryl ketones, using chiral BINOL derivatives.
متن کاملMe2Zn mediated, tert-butylhydroperoxide promoted, catalytic enantioselective Reformatsky reaction with aldehydes.
A practical and highly enantioselective catalytic Reformatsky reaction with aldehydes using a cheap, commercially available aminoalcohol as ligand is described.
متن کاملRecent Advances in the Catalytic Pauson–Khand-Type Reaction
The Pauson–Khand-type reaction is formally a [2+2+1] cycloaddition involving an alkyne, an alkene and carbon monoxide catalyzed or mediated by transition metal complexes. This review focuses on the catalytic reaction and describes the recent research on the Pauson–Khand-type reaction.
متن کاملRecent developments in the asymmetric Reformatsky-type reaction
This review collects the most important developments in asymmetric Reformatsky-type reactions published since the beginning of 2013, including both diastereoselective methodologies based on the use of chiral substrates and enantioselective catalytic procedures.
متن کاملFirst enantioselective one-pot, three-component imino Reformatsky reaction*
The Reformatsky reaction is the well-recognized carbon–carbon bond-forming reaction of α-halo esters with aldehydes or ketones in the presence of Zn metal to give β-hydroxy esters. Recently, it has been reported that Rhand Ni-catalyzed Reformatsky reaction, in which R2Zn (R = Me, Et) acts as the Zn source, reacted smoothly with carbonyl compounds and imines. Taking advantage of N-methylephedrin...
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ژورنال
عنوان ژورنال: European Journal of Organic Chemistry
سال: 2013
ISSN: 1434-193X
DOI: 10.1002/ejoc.201300571